Propylene Oxide

    • Product Name: Propylene Oxide
    • Chemical Name (IUPAC): 2-methyloxirane
    • CAS No.: 75-56-9
    • Chemical Formula: C3H6O
    • Form/Physical State: Liquid
    • Factroy Site: No. 86 Daqiao Road, Lijin County, Dongying, Shandong, China (Headquarters)
    • Price Inquiry: sales3@ascent-chem.com
    • Manufacturer: Lihuayi Group Co., Ltd
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    Specifications

    HS Code

    658222

    Chemicalname Propylene Oxide
    Casnumber 75-56-9
    Molecularformula C3H6O
    Molarmass 58.08 g/mol
    Appearance Colorless liquid
    Odor Ether-like
    Boilingpoint 34°C
    Meltingpoint -112°C
    Density 0.830 g/cm3 (at 20°C)
    Solubilityinwater Miscible
    Vaporpressure 442 mmHg (at 20°C)
    Flammability Highly flammable
    Flashpoint -37°C (closed cup)
    Autoignitiontemperature 455°C
    Refractiveindex 1.3677 (at 20°C)

    As an accredited Propylene Oxide factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.

    Application of Propylene Oxide

    Purity 99.5%: Propylene Oxide with purity 99.5% is used in polyurethane foam manufacturing, where it delivers consistent polymer expansion and optimal cell structure.

    Viscosity 0.36 mPa·s: Propylene Oxide with viscosity 0.36 mPa·s is used in automotive brake fluid production, where it ensures rapid blending and uniform fluid performance.

    Molecular Weight 58.08 g/mol: Propylene Oxide with molecular weight 58.08 g/mol is used in surfactant synthesis, where it imparts high emulsification efficiency and improved solubility.

    Stability Temperature up to 40°C: Propylene Oxide with stability temperature up to 40°C is used in fumigation processes, where it maintains volatile activity for effective sterilization.

    Melting Point −112°C: Propylene Oxide with melting point −112°C is used in aerosol propellant formulations, where it remains in a liquid state under refrigeration for efficient dispersion.

    Water Content ≤0.05%: Propylene Oxide with water content ≤0.05% is used in pharmaceutical intermediate production, where it prevents hydrolysis and maintains product purity.

    Color (APHA) ≤10: Propylene Oxide with color (APHA) ≤10 is used in food additive synthesis, where it provides high product clarity and reduced discoloration risk.

    Peroxide Content ≤1 ppm: Propylene Oxide with peroxide content ≤1 ppm is used in polyol manufacturing, where it reduces oxidative side reactions and enhances final polymer quality.

    Packing & Storage
    Packing Propylene Oxide is typically packaged in 200-liter steel drums with secure, sealed lids, clearly labeled with hazard and handling information.
    Container Loading (20′ FCL) Propylene Oxide is typically shipped in 20′ FCL containers, packed in ISO tanks or steel drums, ensuring safety and regulatory compliance.
    Shipping Propylene Oxide is shipped as a flammable, toxic liquid in pressure-tight, temperature-controlled, stainless steel or aluminum containers or tank cars. It must be kept away from heat, sparks, and incompatible materials. Proper labeling, ventilation, and emergency procedures are essential for safe handling during transport in accordance with regulatory guidelines.
    Storage Propylene Oxide should be stored in tightly closed, stainless steel or aluminum containers in a cool, dry, well-ventilated area, away from heat, flames, and direct sunlight. It must be isolated from acids, bases, oxidizers, and amines. Proper grounding and bonding are required to prevent static discharge. Suitable fire protection and spill containment measures must be in place.
    Shelf Life Propylene oxide typically has a shelf life of 12 months when stored in tightly sealed containers, away from heat, moisture, and direct sunlight.
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    More Introduction

    Propylene Oxide: Production Insight and Real-World Application

    What Sets Propylene Oxide Apart in Modern Industry

    Propylene oxide occupies a distinct space in our plant's lineup of key industrial molecules. Over years of hands-on production, our team has learned that understanding the nuances of this compound gives our partners across the chemical, plastics, and automotive sectors reliable performance. The product we consistently manufacture carries a purity standard above 99.9%, produced through a chlorohydrin process using carefully selected feedstocks that minimize by-products. Our propylene oxide stands out for its stability during storage and transport, thanks to advanced inhibitor systems and precise distillation at each batch.

    Those who work with flexible polyurethane foams or glycols know the difference between consistent gauge and batch-to-batch purity. Minor impurities can throw off downstream polymerization or catalysis, especially in sensitive foaming or polyol synthesis. Keeping careful control in each step, and using robust vessel linings and closed-loop recycling, allows us to guarantee a water-clear liquid that has low acidity and negligible trace metals. We know our clients need more than a “commodity chemical”—they need reliability that keeps their operations running at capacity, cutting unplanned shutdowns and costly clean-outs.

    Model and Specifications: Practical Highlights from Production

    Over multiple expansion projects at our facility, we have adapted our lines to meet a purity that exceeds technical grade and often approaches pharmaceutical standards, though most output targets the polyether polyol market. Output sees regular testing for propylene glycol and allyl alcohol residuals, keeping limits well below the industry’s tightest thresholds. Our standard product enters the market with moisture consistently below 100 ppm, and peroxide values managed aggressively under 10 ppm using nitrogen blanketing. These details matter less to the average end user, but anyone running continuous reactors for polyurethane foam will see the cost savings in catalyst life and process uptime.

    Propylene oxide brings shipping considerations. Its volatility and low boiling point—34°C under atmospheric pressure—make temperature control and expert packaging necessary from our loading bay to end-user tank. We draw from long experience working with shippers to reduce polymer buildup or vent losses, since oxidation or contamination not only cuts into yield but can also present hazards in plant settings. Knowledge of this behavior shapes our logistics solutions, using tank cars with specialized linings, continuous vapor monitoring, and tracked temperature control, especially across long-haul exports.

    Customer Applications from Our Shop Floor to Your Operation

    Most of our propylene oxide gets sent out to partners making polyether polyols for foam furniture, automotive seating, and insulation panels. These producers depend on consistent performance during high-throughput foaming, where even slight variations in reactants can spell poor foam quality, inconsistent density, or batch rejections. We put in the legwork upstream, so our customers seldom have to worry about downstream headaches. Over years of feedback and lab support, issues such as catalyst fouling, uneven polymerization, or excessive VOC release in end products have led us to tweak distillation setups, scrubber units, and tank passivation methods.

    Beyond foams, propylene oxide adds value in producing propylene glycol. Many manufacturers use our output to feed lines that generate glycol for deicing fluids or for solvent base stocks. In these cases, lower chlorinated byproducts and high throughput are essential, since glycol production by hydrolysis can amplify any off-qualities in the feedstock. Our team has coordinated joint R&D cycles with glycol customers, making stepwise purity enhancements and refining temperature controls during loading and unloading, providing better efficiency and fewer unexpected stoppages in their continuous hydrolysis columns.

    Another critical market includes solvents and fumigants where ease of vaporization and consistent reactivity define operational safety and effectiveness. For customers involved in specialty chemical synthesis, epoxy derivatives or flame retardants, our accuracy in maintaining low residual peroxides and stabilizer content proves especially important. This precision comes from detailed in-process monitoring—something we develop not only for our own audits but as an extra layer of robustness so our clients can trust their own manufacturing lines are not relying on luck.

    Comparing Propylene Oxide to Other Epoxides and Commodity Chemicals

    While other oxiranes like ethylene oxide share some application overlap with propylene oxide, experience has shown us that not all epoxides deliver the same operational performance. Ethylene oxide, with its smaller structure and higher reactivity, makes it more aggressive in certain syntheses—an advantage in glycol production but a riskier choice with regard to handling due to higher toxicity and stricter regulatory scrutiny. In our operations, propylene oxide presents a lower personal exposure risk and brings easier containment and rapid neutralization in case of accidental leaks.

    Propylene oxide differs from solvents or basic feedstocks like acetone or methanol, as its epoxide ring offers greater reactivity with nucleophiles, yet remains controllable in closed processing systems. Regular users in the resins and adhesives sector benefit from predictable ring-opening chemistry, which is less sensitive to humidity and ambient temperature fluctuations than many alternative raw materials. Its favorable balance of molecular weight and volatility enables quick mixing and fast throughput without runaway reactions or “gummed up” machinery—a more practical route for engineers needing consistency under tough time constraints.

    In our shop, operators and QA labs never confuse propylene oxide with commodity solvents or unrelated glycols. The cleanliness requirements, inhibitor controls, and monitoring protocols push this product into a unique category. Years back, we dealt with cross-contamination issues between epoxides and non-reactive solvents. Having invested in dedicated pipeline systems and rigorous plant-wide segregation, we now avoid such headaches—saving troubleshooting time and ensuring that customers never receive out-of-specification material.

    Handling, Storage, and Safety: Real Factory Practices

    Producing propylene oxide calls for a culture of respect and precision. Leaks, pressure swings, or unplanned temperature spikes can trigger polymerization or build-up of hazardous vapors. Training and equipment matter. Our staff tour each new operator through hands-on safety modules and simulate unusual scenarios, such as inhibitor depletion or off-gas build-up. During shipment, loading samples are pulled and checked for off-odors and color, since visible haze or a sweet, bitterness in the aroma hint at heat history or exposure to incompatible materials.

    Bulk storage employs climate-controlled spheres or tanks fitted with floating roof seals. We regularly check for inhibitor concentration, and run gas chromatographs to track any spike in byproducts or water ingress. In warm climates, our outgoing trucks and tankers are scheduled for early morning when ambient temperatures drop and evaporation risk eases. Simple tricks—like covering pipe flanges, using acrylic sight glasses rather than acrylic, and mandatory nitrogen purges—cut loss rates and build trust with recipients down the line.

    Anyone who works around propylene oxide learns to respect its health hazards. Dermal exposure, even to minor leaks, can cause irritation or more severe injury. On our site, personal protective equipment and chemical-resistant gloves see mandatory use, and regular air quality checks signal any upward trend in ppm levels. We see safety not only as regulatory compliance or numbers in a spreadsheet, but as the real measure of a sustainable production operation. Training refreshers and open debriefs turn near-misses into learning conversations, and customer visits offer feedback that shapes our protocols.

    Environmental Considerations: Lessons from Daily Operations

    The propylene oxide process demands strict control on waste water and ventilation streams. At our site, we treat reaction wash water and vent gases with multiple stages of scrubbers and catalytic thermal oxidizers, routinely sampling for chlorinated residues. Tightness in the process loops keeps fugitive emissions well within legal and ethical expectations. Over the years, we phased in lighter inhibitor loads and introduced feedstock purification, which together cut down residual organic content in outflows.

    One area that has evolved rapidly relates to lifecycle analysis and residual product in drums or bulk tanks. We once faced criticism about trace residues left after unloading; now, coordinated tank cleaning and drum recycling efforts keep lost volumes down and prevent environmental releases. Many of our downstream partners have joined this effort, and we exchange data to improve cleaning processes and treatment of container washings, further closing the loop between manufacturing and end-user practice.

    Life extension for production assets also brings its own environmental dividends. Proper material selection in our process lines—favoring high-grade stainless or lined reactors—means less replacement, reduced hazardous waste during turnarounds, and a smaller footprint per ton of product shipped. As customer requirements evolve, we stay engaged with emerging “green chemistry” suggestions for catalytic process upgrades or bio-feedstock trials; still, we never adopt new technology only for trend’s sake, but wait for field and lab data to show genuine, repeatable benefit in yields, emissions, and safety.

    Supply Chain, Quality, and Supporting Our Partners’ Growth

    We recognize that every downstream application faces its own bottlenecks—be it price spikes, feedstock interruptions, or new regulatory red tape. Delivering propylene oxide takes more than plant capacity; it depends on a nuanced understanding of logistics, post-shipment care, and quality assurance. Over time, we have adopted a policy of shipping only with carriers who maintain dedicated transfer hoses, vapor recovery, and tank cleaning procedures. Data logging and temperature records for every trip reassure our partners that product history never gets lost between our site and their gate.

    Our in-house QA teams work with customers to interpret specs—not as numbers, but as indicators of process performance and reliability. For every QC report sent with a batch, we share historical trend lines. This opens dialogue and builds insight: persistent issues often reveal process drift, miscommunication, or new contaminant sources. Sharing expertise around sample preparation or transfer hose purging allows our clients to move beyond troubleshooting, cutting lost time in root cause analysis or “mystery” downtime events.

    Through years working with leading foam producers, hydraulic fluid formulators, or specialty monomer shops, we have helped clients find technical solutions to recurring challenges. Our production engineers regularly run trials with customer-supplied catalysts or blend stabilizers at plant scale, allowing real-world validation before major plant changes. Flexibility matters: knowing when to alter inhibitor packages or introduce a new purification train has, on many occasions, kept customer expansion projects on schedule. While the chemical’s identity stays the same, each bulk shipment reflects accumulated know-how and experience.

    Looking Ahead: Continuous Improvement and Market Responsiveness

    Propylene oxide markets evolve with customer demands, global regulations, and feedstock economics. Our production environment never stays static. As emerging applications in elastomers, resins, or even non-foam isocyanate chemistry arise, we actively collect feedback and benchmark performance in case studies and peer collaborations. Having a mature process platform with robust statistical process control lets us scale variations quickly—pilot testing alternate feedstocks or purification processes under real-world plant conditions.

    Our operators bring a unique perspective, often highlighting issues that specification sheets never capture. Regular plant meetings encourage open sharing—practical fixes that cut downtime or bring a better odor rating to each drum. Continuous maintenance on our filters, pressure relief systems, and condenser lines means fewer surprises for the loading bay crew and more predictable supply for the customer. Incremental gains aggregated over thousands of batches translate into major improvements in cost, safety, and satisfaction.

    Customer site visits cement these open lines of communication. Walking the line beside end-user operators—seeing real problems in filling, blending, or handling—gives us ideas for product tweaks, logistics adjustments, and real support for emerging requirements. We treat every feedback loop as an opportunity to bring our experience in propylene oxide manufacturing closer to the needs of our partners and industries served.

    Summary: Real-World Value Beyond the Product Barrel

    Working day in and day out with propylene oxide does more than churn out tankers—it connects us to customers shaping construction, mobility, appliances, and specialty polymers. The process grows more efficient as learning is applied to every operation, and partnerships extend beyond transactional supply to real troubleshooting and continuous improvement. Tackling technical challenges and complying with strict regulatory standards only elevates the sense of shared responsibility—from the controls room of our facility to the end-users’ shop floor.

    Maintaining this standard is as much about technical excellence as it is about straight communication and responsiveness. Propylene oxide will remain a vital tool for many industries as needs evolve, new products develop, and sustainability expectations continue to grow. Only those involved deeply in the production process appreciate how much know-how, skill, and effort goes into every shipment. We take pride in contributing at the foundation of so many value chains, providing real-world solutions from a manufacturer who understands not only the molecule, but the lives and operations depending on it.